Conditions for the validity of Salaah

Salaah times

Q:

1. If sunset is 6.40, at what time should Salah be performed?

2. If sunrise is 6.25, what is the end time of Fjar Salah?

3. If magrib Salah is performed a few minutes early, will it be valid?

4. If in the absence of a watch, how do we look at the sky to know fajr and maghrib salaah times?